Abstract

This work focuses on the application of an orthogonal array design to the optimization of the facile direct carbonization reaction for the synthesis of neodymium carbonate nanoparticles, were the product particles are prepared based on the direct precipitation of their ingredients. To optimiie the method the influences of the major operating conditions on the dimensions of the neodymium carbonate particles were quantitatively evaluated through the analysis of variance (ANOVA). It was observed that the crystalls of the carbonate salt can be synthesized by controlling neodymium concentration and flow rate, as well as reactor temperature. Based on the results of ANOVA, 0.03 M, 2.5 mL min(-1) and 30 degrees C are the optimum values for the above-mentioend parameters and controlling the parameters at these values yields nanoparticles with the sizes of about of 31 +/- 2 nm. The product of this former stage was next used as the feed for a thermal decomposition procedure which yielding neodymium oxide nanoparticles. The products were studied through X-ray diffraction (XRD), SEM, TEM, FT-IR and thermal analysis techniques. In addition, the photocatalytic activity of dyspersium carbonate and. dyspersium oxide nanoparticles were investigated using degradation of methyl orange (MO) under ultraviolet light. (C) 2017 Elsevier B.V. All rights reserved.