(2020) Study of photocatalytic and electrocatalytic activities of calcium tungstate nanoparticles synthesized via surfactant-supported hydrothermal method. Journal of Materials Science-Materials in Electronics. pp. 20255-20269. ISSN 0957-4522
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Study of photocatalytic and electrocatalytic activities of calcium tungstate nanoparticles synthesized via surfactant-supported hydrothermal method.pdf Download (2MB) |
Abstract
Here, calcium tungstate nanoparticles (CWONPs) were synthesized by the hydrothermal method. The reaction parameters including calcium salt concentration, surfactant concentration, reaction time and temperature have been optimized by Taguchi Design Method for smaller particles size. The morphology, size, crystallinity and chemical structure of nanoparticles were investigated by different methods. The optimized calcium tungstate nanoparticles (opt-CWONPs) with average size of 51 nm were showed outstanding removal effectiveness for three different pollutants including methyl orange, imipenem and imatinib mesylate over UV illumination. Nearly, 100 of methyl orange, 98 of imipenem and 60 of imatinib mesylate are degraded at 1800s overopt-CWONPs with banggap 3.7 eV. In addition, a modified carbon paste electrode was formed withopt-CWONPs and linear sweep voltammetry was used to analyze its electrocatalytical activity in acidic media. The findings showed that the carbon paste electrode modified byopt-CWONPs had a higher current density in the hydrogen evolution reaction (HER) than the bare carbon paste electrode. This article has subsequently revealed a revolutionary method foropt-CWONPs preparation and demonstrated its multifunctionality as photocatalyst and electrocatalyst active ingredients.
Item Type: | Article |
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Keywords: | hydrogen evolution reaction copper-oxide nanoparticles facile chemical-synthesis green synthesis procedure optimization degradation-products imatinib mesylate nanostructures kinetics dye Engineering Materials Science Physics |
Page Range: | pp. 20255-20269 |
Journal or Publication Title: | Journal of Materials Science-Materials in Electronics |
Journal Index: | ISI |
Volume: | 31 |
Number: | 22 |
Identification Number: | https://doi.org/10.1007/s10854-020-04545-7 |
ISSN: | 0957-4522 |
Depositing User: | مهندس مهدی شریفی |
URI: | http://eprints.bmsu.ac.ir/id/eprint/8550 |
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