Repository of Research and Investigative Information

Repository of Research and Investigative Information

Baqiyatallah University of Medical Sciences

Magnetic molecularly imprinted nanoparticles for the solid-phase extraction of diazinon from aqueous medium, followed its determination by HPLC-UV

(2017) Magnetic molecularly imprinted nanoparticles for the solid-phase extraction of diazinon from aqueous medium, followed its determination by HPLC-UV. Journal of Applied Biotechnology Reports. pp. 533-539. ISSN 23221186 (ISSN)

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Abstract

The aim of the present work was to investigate the feasibility of employing the molecular imprinting polymer technique for detecting diazinon using magnetic molecularly imprinted nanoparticles. The magnetic molecularly imprinted nanoparticles were prepared in the presence of a template diazinon molecule. These nanoparticles exhibited a linear response in the range of 2-20 ppm (y = 0.2634×Cdiazinon - 0.0575, R2=0.9892) for detection of diazinon. The adsorption kinetics and isotherms and the selectivity efficiencies of diazinon and other structurally related analogues were investigated by HPLC-UV as well, respectively. The results showed that the magnetic molecularly imprinted nanoparticles have high adsorption capacity, controlled selectivity, and direct magnetic separation in aqueous environments. The results indicates that the spiked recoveries were changed from 73 to 85, and the RSD was lower than 11.91. © All rights reserved for official publication of Baqiyatallah university of medical sciences.

Item Type: Article
Keywords: Adsorption isotherm Adsorption kinetic Diazinon Magnetic molecularly imprinted Nanoparticle Selective recognition
Divisions:
Page Range: pp. 533-539
Journal or Publication Title: Journal of Applied Biotechnology Reports
Journal Index: Scopus
Volume: 4
Number: 1
ISSN: 23221186 (ISSN)
Depositing User: مهندس مهدی شریفی
URI: http://eprints.bmsu.ac.ir/id/eprint/137

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